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Soluble salt removal from MSWI fly ash and its stabilization for safer disposal and recovery as road basement material

Fly ash from municipal solid waste incinerators (MSWI) is classified as hazardous in the European Waste Catalogue. Proper stabilization processes should be required before any management option is put into practice. Due to the inorganic nature of MSWI fly ash, cementitious stabilization processes are worthy of consideration. However, the effectiveness of such processes can be [...]

The use of human urine as an organic fertilizer in the production of okra (Abelmoschus esculentus) in South Eastern Nigeria

Greenhouse and field experiments were conducted to evaluate the response of okra to different levels of human urine (0, 10,000, 15,000 and 20,000 L/ha) and 400 kg/ha NPK 15:15:15 inorganic fertilizer in five riverine communities of Cross River State, Nigeria. The soils of the communities are generally acid with low organic matter, total nitrogen, exchangeable [...]

A One-Pot Method for the Selective Conversion of Hemicellulose from Crop Waste into C5 Sugars and Furfural by Using Solid Acid Catalysts

We present a solid-acid catalyzed one-pot method for the selective conversion of solid hemicellulose without its separation from other lignocellulosic components, such as cellulose and lignin. The reactions were carried out in aqueous and biphasic media to yield xylose, arabinose, and furfural. To overcome the drawbacks posed by mineral acid methods in converting hemicelllulose, we [...]

Use of Industrial Waste for the Manufacturing of Sustainable Building Materials

Presently, appropriate waste management is one of the main requisites for sustainable development; this task is tackled by the material construction industry. The work described herein is focused on the valorization of granite waste through incorporation, as a filler-functional admixture, into cement-based mortar formulations. The main components of the waste are SiO2 (62.1 %), Al2O3 (13.2 %), [...]

Ammonium recovery and energy production from urine by a microbial fuel cell

Nitrogen recovery through NH3 stripping is energy intensive and requires large amounts of chemicals. Therefore, a microbial fuel cell was developed to simultaneously produce energy and recover ammonium. The applied microbial fuel cell used a gas diffusion cathode. The ammonium transport to the cathode occurred due to migration of ammonium and diffusion of ammonia. In [...]

Ammonia as a possible element in an energy infrastructure: catalysts for ammonia decomposition

The possible role of ammonia in a future energy infrastructure is discussed. The review is focused on the catalytic decomposition of ammonia as a key step. Other aspects, such as the catalytic removal of ammonia from gasification product gas or direct ammonia fuel cells, are highlighted as well. The more general question of the integration [...]

A Brief Review on Industrial Alternatives for the Manufacturing of Glycerol Carbonate, a Green Chemical

Glycerol carbonate is one the glycerol derivatives which attracts attention for industrial applications. This review compares strategies for its synthesis, and their analyses lead to the conclusion that (indirect) procedures starting from glycerol- and/or CO2-derivatives are the most attractive. These are described and compared, taking criteria of industrial feasibility into account. As a result, the [...]