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Biomass-derived electrocatalytic composites for hydrogen evolution

The production of hydrogen from water electrolysis calls for an efficient non-precious-metal catalyst to make the process economically viable because of the high cost and the limited supply of the currently used platinum catalysts. Here we present such a catalyst made from earth-abundant molybdenum and common, humble soybeans (MoSoy). This catalyst, composed of a catalytic [...]

Comparative techno-economic analysis of biohydrogen production via bio-oil gasification and bio-oil reforming

This paper evaluates the economic feasibility of biohydrogen production via two bio-oil processing pathways: bio-oil gasification and bio-oil reforming. Both pathways employ fast pyrolysis to produce bio-oil from biomass stock. The two pathways are modeled using Aspen Plus® for a 2000 t d−1 facility. Equipment sizing and cost calculations are based on Aspen Economic Evaluation® [...]

High-Yield Production of Dihydrogen from Xylose by Using a Synthetic Enzyme Cascade in a Cell-Free System

H2 was produced from xylose and water in one reactor containing 13 enzymes (red). By using a novel polyphosphate xylulokinase (XK), xylose was converted into H2 and CO2 with approaching 100 % of the theoretical yield. The findings suggest that cell-free biosystems could produce H2 from biomass xylose at low cost. Xu5P=xylulose 5-phosphate, G6P=glucose 6-phosphate. DOI: [...]

Improving effect of metal and oxide nanoparticles encapsulated in porous silica on fermentative biohydrogen production by Clostridium butyricum

► Encapsulated nanoparticles (NP) were tested for biohydrogen production improvement. ► Pd, Ag, Fe and Cu NP were added in Clostridium butyricum BHP tests. ► Fe NP showed an improvement of the hydrogen volume and rate of production. ► In pH controlled AnSBR, Fe NP showed +113% of hydrogen production rates. ► NP addition had [...]

An energy self-sufficient public building using integrated renewable sources and hydrogen storage

At the moment, the widespread use of renewable energy in buildings is limited by its intrinsic discontinuity: consequently integration of plants with energy storage systems could represent an efficient solution to the problem. Within this frame, hydrogen has shown to be particularly fit in order to be used as an energetic carrier.In this aim, in [...]

Low CO2-emissions hybrid solar combined-cycle power system with methane membrane reforming

Based on the principle of cascade utilization of multiple energy resources, a gas-steam combined cycle power system integrated with solar thermo-chemical fuel conversion and CO2 capture has been proposed and analyzed. The collected solar heat at 550 °C drives the endothermic methane reforming and is converted to the produced syngas chemical exergy, and then released [...]

Aluminium recovery vs. hydrogen production as resource recovery options for fine MSWI bottom ash fraction

Waste incineration bottom ash fine fraction contains a significant amount of aluminium, but previous works have shown that current recovery options based on standard on-step Eddy Current Separation (ECS) have limited efficiency. In this paper, we evaluated the improvement in the efficiency of ECS by using an additional step of crushing and sieving. The efficiency [...]

Low-temperature aqueous-phase methanol dehydrogenation to hydrogen and carbon dioxide

Here we describe an efficient low-temperature aqueous-phase methanol dehydrogenation process, which is facilitated by ruthenium complexes. Hydrogen generation by this method proceeds at 65–95 degrees Celsius and ambient pressure with excellent catalyst turnover frequencies (4,700 per hour) and turnover numbers (exceeding 350,000). This would make the delivery of hydrogen on mobile devices—and hence the use [...]

Comparative techno-economic analysis of biohydrogen production via bio-oil gasification and bio-oil reforming

This paper evaluates the economic feasibility of biohydrogen production via two bio-oil processing pathways: bio-oil gasification and bio-oil reforming. Both pathways employ fast pyrolysis to produce bio-oil from biomass stock. The two pathways are modeled using Aspen Plus® for a 2000 t d−1 facility. Equipment sizing and cost calculations are based on Aspen Economic Evaluation® [...]

Synthesis of Nanovoid Bi2WO6 2D Ordered Arrays as Photoanodes for Photoelectrochemical Water Splitting

Herein we report a facile and economic method to prepare nanovoid Bi2WO6 2D ordered arrays employing a simple self-assembly procedure. The electrochemical properties and performance of the 2D nanoarray as a photoanode for water splitting are investigated and compared with a conventional photoanode of similar thickness. The 2D array photoanode shows a much higher photocurrent [...]